TEMPERATURE SWING ADSORPTION PROCESSES FOR GAS SEPARATION

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TEMPERATURE SWING ADSORPTION PROCESSES FOR GAS SEPARATION ( temperature-swing-adsorption-processes-for-gas-separation )

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Table C.3 Sample calculations for the governing conservation equations – continued r 106 [m] crystal  7.210-12 [m2 s-1] D  5.910-11 [m2 s-1] D crystal ,CH 4 crystal ,CO2 Ct = 1659 [mol m-3 ] A,CH4 , j Ct = 5205 [mol m-3 ] A,CO2 , j t  0.005 [s]  4.1510-12 [kPa-1]  4.5010-12 [kPa-1]  20400 [J mol-1 ]  25000 [J mol-1 ] R  8.314 [J mol-1 K-1] Ttt 306.5[K] w, j b 0,CH4 b 0,CO2 Q B,CH4 Q B,CH4  3.918 [mol kg-1]  4.161 [mol kg-1] Ct  23.68 [kg m-3] w,CH4 , j Ct  29.18 [kg m-3] w,CO2 , j M B,CH4 M D,CO2 ads  1760[kgm-3] LDF constant K 15Dcrystal,i LDF,i r 2 crystal LDF Equation CA,i K t C LDF ,i A,Eq,i C  A,i Discretized form Ctt Ct K A,i, j A,i, j tt C Auxiliary parameters for adsorbent capacity determination t B b expQB,i  tt A,Eq,i, j C tt A,i, j  Btt b exp QB,i   i,j 0i RTtt   w,j  LDF ,i, j i 0i RT w Isotherm equation for silicalite BP CMii A,Eq,i ads B,i1BP   CttMi,ji,j  ii i    Btt Ptt  ads  B,i 1Btt Ptt  A,Eq,i,j Gas partial pressure P  Cw,i RuTw i Ctt RTtt Ptt  w,i,j w,j i,j i, j i,j   MWi  i MWi K 108 [s-1] LDF,CH4 K Ctt  885 [s-1 ] 1654 [mol m-3]  5200 [mol m-3] LDF ,CO2 A,CH4,j Ctt A,CO2 , j Ctt A,Eq,H4 , j 1647 [mol m-3] Ctt  5198 [mol m-3] A,Eq,CO2 , j Btt 1.2103 [kPa-1] CH4,j Btt  8.0103 [kPa-1] CO2,j Ptt 3749[kPa] CH4,j Ptt 1686 [kPa] CO2,j 190

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