TEMPERATURE SWING ADSORPTION PROCESSES FOR GAS SEPARATION

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TEMPERATURE SWING ADSORPTION PROCESSES FOR GAS SEPARATION ( temperature-swing-adsorption-processes-for-gas-separation )

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Table D.2. Sample calculations for governing equations in the laboratory scale models – continued  10.10[s-1]  92.87[s-1] = 0 [mol m-3 ] = 13.825 [mol m-3 ] = 2018.695 [mol m-3 ] t  0.005 [s] K LDF,N2 LDF ,CO2 K Ct A,He,j Ct A,N2,j Ct A,CO2 , j b 0,N2 b 0,CO2 d d 3.7310-5 [kPa-1]  3.3210-7 [kPa-1] Q 0,N2 0,CO2 3.1810-5 [kPa-1]  6.4310-7 [kPa-1]  7528.1 [J mol-1 ]  41077.1 [J mol-1 ]  7941.2 [J mol-1 ]  29812 [J mol-1] B,N2 Q B,CO2 Q D,N2 Q D,CO2 R8.314[Jmol-1 K-1] Ttt 300.3177[K] w,j M M M M B,N2 B,CO2 D,N2 D,CO2 1.4339 [mol kg-1]  0.9266 [mol kg-1] 1.4339 [mol kg-1]  2.9791 [mol kg-1]  1480[kgm-3] ads Ptt 100.11[kPa] He,j Ptt 8.5197[kPa] N2 , j Ptt 3.3444[kPa] CO2,j For zeolite 5A using DSL BPDP CMiiMii A,Eq,i ads  B,i 1B P D,i 1 D P      Ctt  M ii  Dtt  Ptt  i, j i,j  ii ii Btt  Ptt i, j i,j M A,Eq,i, j ads  B,i 1 Btt  Ptt D,i 1  Auxiliary parameters for adsorbent capacity determination Q BttbexpQB,i  B b exp B,i i,j i 0i RT 0i  tt  RT  w,j  Q  Dtt d expQD,i   w  Ddexpd,i i,j 0i tt i 0i RT  w  LDF Equation RT  w,j   Dtt  Ptt i, j i,j    i, j i,j ii CA,i K C C  t Ctt Ct K LDF,i A,Eq,i A,i C H Q M B1DP2Q M D1BP2 A,i, j A,i, j tt tt A,Eq,i, j tt A,i, j t ads,i LDF ,i, j Heat of adsorption  M B1DP2M D1BP2 B,i i i i D,i i i i 2 C B,i B,i i i i D,i D,i i i i Htt  ads,i i,j i,j tt tt  tt tt  Q M B 1D P B,i B,i i,j i,j i,j tt tt  tt tt  Q M D 1B P D,i D,i i,j tt tt  tt tt  2 2 M B 1D P B,i i,j i,j i,j 2 M tt tt  tt tt  D  1B P D,i i,j i,j i,j Ctt A,N2,j Ctt A,CO2 , j 12.35 [mol m-3]  2347 [mol m-3] Ctt A,Eq,N2,j 11.18 [mol m-3] Ctt  2375 [mol m-3] A,Eq,CO2 , j Btt 7.6104 [kPa-1] N2,j Btt  4.63 [kPa-1] CO2,j Dtt 7.6104 [kPa-1] N2,j Dtt  0.0985 [kPa-1] CO2,j Htt ads,He Htt ads,N2 Htt ads,CO2  0 [J mol-1] 17.14 [J mol-1]  30790 [J mol-1] 209

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