CO2 Conversion in a Microwave Plasma Catalyst System

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CO2 Conversion in a Microwave Plasma Catalyst System ( co2-conversion-a-microwave-plasma-catalyst-system )

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CHAPTER IV Preliminary Investigation in a Helicon Source In Chapter III the physical processes in plasmas were discussed along with the characteristics of RF and MW discharges. Vibrational excitation was cited as the most effective means of CO2 dissociation and the required plasma properties to achieve this were defined. In the following chapter, a preliminary experimental investigation of CO2 dissociation in a RF plasma is discussed. First, a hypothesis will be given in Section 4.1 explaining the benefits of a RF plasma for CO2 dissociation. Then the experimental setup and diagnostic tools will be described in Section 4.2. Section 4.3 gives the experimental results while Section 4.4 considers the basic energy efficiency requirements for such a plasma system to be viable for carbon emissions mitigation. Lastly, Section 4.5 provides some conclusions. 4.1 Hypothesis 4.1.1 Benefits of Helicon Source The RF plasma used in this experiment is a low-pressure helicon discharge. As described in section 3.2, one of the essential requirements for stimulating vibrational excitation of CO2 is creating thermal non-equilibrium between the electron temperature and the neutral gas temperature. Low-pressure RF plasmas are known for their non- thermal characteristics and have the ability to operate in three different modes, 65

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