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results of energy and conversion efficieny for a fixed pressure of 120 torr. Energy efficiency peaks at 80% with a corresponding conversion efficiency of about 20% [37]. Conversion efficiency continues to increase with higher values of Ev, while η begins to decline. However the addition of catalyst material may be able to boost conversion efficiency while maintaining energy efficiency, as discussed in Section 3.3. (a) (b) Figure 5.2: Efficiencies of CO2 dissociation in a microwave plasma at 120 torr: a) energy efficiency, and b) conversion efficiency. 1) and 2) are data points from different mass-spectral measurements, 3) data from manometric measurements, 4) data from flow-control-based measurements [37]. Another drawback of this microwave system is that it requires the use of a vacuum pump to maintain the pressure around 100 torr. When looking to scale up the system for industrial operation, a vacuum pump brings added cost/energy and complexity. Thus, a system that can achieve similar energy efficiencies at atmospheric pressure would be ideal. Surface wave discharges excited by microwaves have the potential to achieve non-thermal conditions at atmospheric pressure. Figure 5.3 shows spectroscopic results of temperature and density from a surface wave plasma at atmospheric pressure 81PDF Image | CO2 Conversion in a Microwave Plasma Catalyst System
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