CO2 Conversion in a Microwave Plasma Catalyst System

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CO2 Conversion in a Microwave Plasma Catalyst System ( co2-conversion-a-microwave-plasma-catalyst-system )

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determined for a 2.45 GHz wave to be 0.2 W/cm per kW incident microwave power, which is comparable to that of quartz making it an attractive choice for use with mi- crowave plasmas [90]. Figure 5.6 shows the optical and IR transmission characteristics of the fluid, indicating near 100% transmission in the optical region. A 5-centistokes viscosity PDMS fluid purchased from Clearco passes through a recirculating chiller with heat exchanger, Polyscience Model 6860T, to regulate the fluid at a desired temperature as it cools the discharge tube. For all experiments, the PDMS was set to 7°C and varied on average ±3°C during operation. The PDMS was injected into the cooling jacket via ports of 0.95-cm quartz tubing. Images of the discharge tube with cooling jacket are shown in Figure 5.7. (a) (b) Figure 5.7: Discharge tube with cooling jacket: a) illustration of discharge tube, b) picture of actual discharge tube. 5.3 Catalyst Material 5.3.1 Rhodium-Coated Monoliths The catalyst material was designed and constructed through collaboration with the University of Michigan Chemical Engineering Department. One of the simplest methods of introducing the catalyst into the plasma system is via cylindrical honeycomb structures called monoliths. Figure 5.8a shows a picture of the actual catalyst monoliths 89

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