CO2 Conversion in a Microwave Plasma Catalyst System

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CO2 Conversion in a Microwave Plasma Catalyst System ( co2-conversion-a-microwave-plasma-catalyst-system )

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corrected spectrum for the experimentally observed C2 Swan Band system. Figure 5.13: Relative vs. corrected spectrum of the C2 Swan Band Temperature analysis of the emission spectrum is performed using the program SPECAIR version 2.2 available for free download here [15]. SPECAIR is a radiative modeling program used to model the absolute intensity spectral radiation emitted by air plasmas in the range of 80 nm to 5.5 μm. This is a widely used program for analyzing atmospheric pressure air plasmas as shown here [59,63,95,97,100]. SPECAIR specializes in air plasma species and can model 37 molecular transitions of NO, N2, N+2 , O2, CN, OH, NH, C2, and CO as well as the atomic lines of N, O, and C. The program has several user inputs including different values for electronic, rotational, translational, and vibrational temperatures. The system specifications include operating pressure, wavelength range, species mole fractions, and radiative transitions. For the given user inputs, SPECAIR will output a simulated spectrum which can be compared to experimental results. Thus by varying the temperature inputs for a specific operating condition until the computed spectrum matches the 96

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