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Figure 6.11: Effects of Tr on SPECAIR spectrum. Simulated for experimental condition Ar:CO2 = 10:1 at 1 kW with constant Tv = 7600 K and Tel = 13900 K. decrease in the intensity of the (1,0) band and decreases for the other two bands as well. Additionally, all three bands experience a narrowing of band width. Unlike vibrational and rotational temperature, the electronic temperature has the most influence over the intensity of atomic oxygen emission lines, particularly the 777 nm line relevant for this experimental spectrum. Figure 6.13 illustrates the changes electronic temperature will have on the simulated spectrum. With constant Tv = 7600 K and Tr = 6050 K, the electronic temperature of 13900 K provided the best match to the experimental spectrum. A decrease in temperature to 10900 K results in a drastic reduction in emission intensity for the 777-nm line, but does not significantly affect the Swan system. When the temperature increases to 16900 K, the emission intensity exceeds that of the experimental 777 nm line, and also causes a large drop in intensity and band width for the entire Swan system. 119PDF Image | CO2 Conversion in a Microwave Plasma Catalyst System
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