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CO2 Conversion in a Microwave Plasma Catalyst System

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CO2 Conversion in a Microwave Plasma Catalyst System ( co2-conversion-a-microwave-plasma-catalyst-system )

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Figure 6.21: Computational conversion efficiencies for Ar flow rate of 10 slm, CO2 flow rate from 1-8 slm , and 1-2 kW of power. 6.3.2 Simulated Plasma Properties Through Equations 5.15 and 5.16, GlobalKin can compute the electron temperature and gas temperature in the simulated plasma. Since the model is run in plug flow mode, species densities and plasma temperatures are given as a function of axial position along the discharge tube. For accurate comparison with the optical emission temperature results of the experimental system, the simulated temperature and electron density values are taken at the center of the discharge tube, close to the position of the light-collecting collimating lens. In this location the experimental plasma was its brightest and hottest, and where most of the plasma-chemical reactions took place. The results for Te are shown in Figure 6.23. The simulated plasma electron temperature increases monotonically with specific energy, while the experimentally measured temperature is unaffected by Ev. The computational results imply that as the molar fraction of CO2 increases at low Ev, the electron energy decreases as it is transferred to heavy particles via collisions. However, the electrons maintain more energy in the simulated plasma than in the experimental plasma, since Te is nearly 132

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