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Figure 6.23: Computational electron temperature. Similarly Equation 5.15 (describing Te), shows that collisions are the main loss process. Given that the simulated Te is higher and the simulated Tg is lower than the experimental results, it is likely that some important collisional processes have been excluded from the model which could affect the plasma temperatures. The simulated temperatures indicate that not as much collisional energy is being transfered from electrons to heavy particles. The simulated plasma electron density is plotted in Figure 6.25. There is a trend of decreasing electron density with decreasing Ev that mimics the electron temperature trend. It is expected that for a given power level, lower CO2 flow rates (higher Ev) result in more energy available per molecule, which can stimulate more dissociation and ionization events. Unfortunately there are no experimental results of electron density for comparison, though the simulated ne can be compared to other reported experimental systems. In the systems summarized by Figure 5.3b, the electron density was experimentally determined to be in the range of 1 − 9 × 1014 cm−3 for atomic gases He, Ar, and Ne. Other reports of pure Ar discharges at atmospheric pressure has shown ne reach 1015 cm−3 [51,73]. However for an N2 + 1.6% H2 discharge operating at atmospheric pressure, the electron density drops to around 8 × 1012 cm−3 [36]. Thus 134PDF Image | CO2 Conversion in a Microwave Plasma Catalyst System
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