HYDROMETALLURGICAL TREATMENT OF E-SCRAP

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HYDROMETALLURGICAL TREATMENT OF E-SCRAP ( hydrometallurgical-treatment-e-scrap )

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an iodine-iodide solution. The results indicated that more than 99% of gold was dissolved, while less than 1% of silver and palladium were dissolved at the conditions: iodine/iodide mass ratio of 1/6, pulp density of 10%, agitation speed of 500 rpm, 24 hours and 40°C. Moreover, approximately 99.8% of gold could be recovered by NaOH precipitation with a 0.6 ml/ml dosage of L-AA at pH 1.9. 3.4 Bromine Leaching Bromine with atomic number 35 is used in the production of clear brines for the oil drilling industry, bromine-based biocides for water treatment, and brominated flammable retardants (Lyday, 2002). Bromine is a reactive element and mostly found in the form of inorganic salts in seawater, evaporitic lakes, and underground brines (Schnebele, 2018). Bromine, a volatile reddish- brown, highly corrosive liquid, can be produced by chlorine oxidation of bromide, followed by absorption and purification. Bromine is the key element in the production of brominated flammable retardants, which are the detrimental compound for printed circuit boards; thus, it will be beneficial to investigate the bromine chemistry in the extraction of precious metals. 3.4.1 Bromine Chemistry Liquid bromine is denser than water and soluble in water (solubility: 0.214 mol/L at 25 °C) (PubChem, 2018). For a stable bromine-water system, Fig. 3.2 shows the stable bromide species at room temperature (25 °C). The bromine is present as aqueous species in the red region, in which the reaction (Eq. 3.8) occurs. Br2(aq) = Br2(l) (3.8) The formation of tribromide ions shown in the yellow region could be expressed either by Eq. 3.9 or Eq. 3.10. Br3- + 2e = 3Br- (3.9) Br2 + Br- = Br3- (3.10) Other than Br2 and Br3-, BrO3- , BrO4- and Br- can also be found in the diagram. As shown in Fig. 3.3 and 3.4, at Eh = 0.8 V, the Br- species predominates in the pH range of 0 to 11; however, Br-, Br2 and Br3- become the dominant species when the Eh in the solution is up to 1 V. The increasing concentrations of Br2 and Br3- will further have a positive effect on oxidizing the 25

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