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CHAPTER 4 CHARACTERIZATION This chapter summarizes the main analytic techniques, and details the sample preparation as well as characterization of waste printed circuit boards (WPCBs) obtained from Aurubis. Mineral liberation analysis (MLA) of the WPCBs was conducted by the Center for Advanced Mineral and Metallurgical Processing (CAMP), at Montana Tech of the University of Montana. Quantitative evaluation of characterization by scanning electron microscope (QEMSCAN), atomic absorption spectroscopy, and inductively coupled plasma mass spectrometry (ICP-MS), is conducted at Colorado School of Mines. Characterization information may qualitatively and quantitatively guide the methodology to efficiently separate desirable metals from waste printed circuit boards. 4.1 Theories of Analytical Techniques An illustration of theories for the analytical techniques will be helpful to better and more clearly understand and identify the mineralogical information of waste printed circuit boards presented in this dissertation. 4.1.1 Mineral Liberation Analyzer Scanning Electron Microscope (MLA-SEM) The mineral liberation analyzer scanning electron microscope (MLA-SEM) is an automated mineral analysis system that is capable of identifying minerals in polished sections and quantifying a wide range of mineral qualities, such as grain size, mineral association, and abundance. A MLA-SEM system consists of a large specimen chamber automated Scanning Electron Microscope (SEM), multiple Energy Dispersive X-ray detectors, and automated quantitative mineralogy software. Similar to SEM, the MLA analysis requires a proper sample preparation where the sample is prepared as flat polished surfaces, coated with a thin conductive film, usually carbon. Basically, the analysis is performed by combining backscattered (BSE) image analysis with x-ray mineral identification, which generally includes three types of x-ray analytical techniques, point x-ray analysis, area x-ray analysis, and x-ray mapping (Fandrich R. et al., 2007). Identification can be achieved by imaging mineral grains, where the BSE brightness of the minerals are varied; however, particle X-ray mapping can analyze elemental information by 34PDF Image | HYDROMETALLURGICAL TREATMENT OF E-SCRAP
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