HYDROMETALLURGICAL TREATMENT OF E-SCRAP

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HYDROMETALLURGICAL TREATMENT OF E-SCRAP ( hydrometallurgical-treatment-e-scrap )

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100.00 90.00 80.00 70.00 60.00 50.00 40.00 30.00 20.00 10.00 0.00 0 2 4 6 8 10 12 Time (hr) Ni Cu Zn Sn Sb Pd Ag Au Figure 6.14 Bromine leaching of shredded waste printed circuit boards in the presence of 5% HCl (0.77M Br2, 1.17M NaBr, 400 RPM, 23.5 °C and natural pH) To characterize the leaching residue from the triplicate experiments, a SEM-EDS analysis was conducted. Prior to the SEM analysis, the leaching residue was first ground and then rinsed by deionized water and acetone in order to eliminate the bromine effect and liberate the leaching residue of the waste printed circuit boards. Fig. 6.16 shows the elemental composition of Point A which is found in Fig. 6.15. This figure shows the presence of bromine, silver and silicon. As shown in Fig. 6.17 and Fig. 6.18, it is obvious that there is a gold particle having a particle size of 50 μm. The reason that the gold was not dissolved during the leaching process is that the gold was not well liberated. Since the residue was further ground before the SEM analysis, the gold was exposed and shown in Fig. 6.17. Copper and tin can be also identified as shown in Fig. 6.19. In sum, the results from SEM-EDS are in accordance with the ICP-MS analysis. 79 Metal dissolved (%)

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