Supercritical Fluids and Their Application to the Recycling of High-Performance Carbon Fibre Reinforced Composite Materials

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Supercritical Fluids and Their Application to the Recycling of High-Performance Carbon Fibre Reinforced Composite Materials ( supercritical-fluids-and-their-application-recycling-high-pe )

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significantly lower than that of PEEK, in some cases the mass loss appears linear below 600 K. It is therefore suggested that the TGA data for samples processed for longer than 30 minutes show the thermal degradation of the PEEK decomposition products, and not that of the polymer. The absence of a sharp increase in thermal degradation rate at 848 K further implies that the polymer decomposition is essentially complete for reaction times in excess of 30 minutes. When the processing time is 0 minutes there is insufficient time for the decomposition to take place. However, prior to obtaining the reaction temperature of 623 K PEEK undergoes a transition to the melt phase at 616 K. Figure 47 and Figure 50 demonstrate that there is a synergistic effect between the ethanol and caesium carbonate concentrations. Experiments using 100 %v ethanol have shown that decomposition of the polymer did not take place, the solid samples were swollen but not degraded. It is known that Cs2CO3 is soluble in both water and ethanol, and also in mixtures of both solvents. It is suggested that ethanol / water mixture, being at its critical point, swells the PEEK allowing for an increased mass transport of the Cs2CO3 carried in the ethanol / water mixture into the PEEK structure. Similar material expansion and subsequent porosity has been identified with supercritical water (scH2O). This similarity in the expansion of PEEK is thought to be accountable for the ability of Cs2CO3 in ethanol / water mixtures to decompose PEEK at 80 K below what is possible with water / Na2CO3 solutions. When the reaction medium consists of ethanol and the reaction time is 0 minutes, an increase in the solid mass recovered from the reactor is observed. The SEM data have 194

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