Supercritical Fluids and Their Application to the Recycling of High-Performance Carbon Fibre Reinforced Composite Materials

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Supercritical Fluids and Their Application to the Recycling of High-Performance Carbon Fibre Reinforced Composite Materials ( supercritical-fluids-and-their-application-recycling-high-pe )

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15 10 5 0 -5 -10 -15 Virgin PEEK150CA30 [Cs2CO3] = 1 mg ml-1 [Cs2CO3] = 4 mg ml-1 [Cs2CO3] = 6 mg ml-1 [Cs2CO3] = 8 mg ml-1 300 400 500 600 700 Temperature (K) Figure 64: DSC thermograms for PEEK 150CA30 processed for 30 minutes using [PrOH] = 20 %v, [H2O] = 80 %v, 16.4 ± 0.4 MPa, 1 - 8 mg ml-1 Cs2CO3 Inspection of Figure 64 shows that the polymer transitions, in particular the melt temperature (Tm), are prominent when the caesium carbonate concentration is up to 8 mg ml-1. There is a noticeable reduction in the Tm for all samples irrespective of the caesium carbonate concentration when compared to the virgin PEEK sample. The reduction in Tm for the processed samples may be due to the partial decomposition of a proportion of the polymer chains, leading to an increased polydispersity index (PDI) (not measure during this research). Should this occur, some decomposition products would exist and, having a different decomposition temperature to PEEK, could potentially decompose prematurely. This is consistent with empirical observation; inspection of Figure 64 shows that for samples processed with a [Cs2CO3] of 4, 6 and 8 mg ml-1, an exotherm is visible immediately after the Tm. It is also noted that when [Cs2CO3] was 8 mg ml-1 the onset of the exotherm occurred prior to the Tm, with the sample becoming exothermic at approximately 510 K. 203 Heat Flow (mW)

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