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1.3. THESIS OUTLINE 1. GENERAL INTRODUCTION in CO2 asymmetric stretch mode with a special focus on vibrational up-pumping. The fluid model introduced in chapyer 4, is extended to test the efficiency of CO2 dissociation from vibrationally excited mo- lecules. Two types of calculations will be discussed: First, initial levels of vibrational modes are included and a detailed study of loss and de- struction process of the initial states is done.; Second, in addition to the species included in the first study vibrationally excited species in asymmetric mode up to dissociation limit are included to evaluate the rates of dissociation by vibrational up-pumping. Only collisional in- duced excitation from molecules excited in the asymmetric mode and collisional de-activation to lower levels in only asymmetric mode have been included for the higher levels in the second study. These specific, but limited population processes are included in the second study so as to evaluate the upper-bound where maximum energy efficiency can be achieved, that is, predominantly by vibrational up-pumping. However, it is shown that compared with electron impact dissociation, vibrational up-pumping is very weak in a DBD. 9PDF Image | Understanding CO2 containing non-equilibrium plasmas
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