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Understanding CO2 containing non-equilibrium plasmas

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Understanding CO2 containing non-equilibrium plasmas ( understanding-co2-containing-non-equilibrium-plasmas )

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5.9. RESULTS & DISCUSSION these are typical values then the values that τc reach are in the order of 10−6 s or frequen- cies in the range of MHz. However, it has to be noted that at Um suggested for optimal vibrational excitation (1-2 eV), kDR decreases by one order of magnitude bringing the frequencies closer to the ones used in typical DBDs (100 kHz). Hence, DBDs can be successful in promoting vibrational excitation only if ionization cost can be reduced. 5.9.3 VV up-pumping along asymmetric mode (ν3) For study B, 20 vibrational levels of asymmetric mode are included and the vibrational distributions are calculated for the conditions listed in table 5.2. Initial populations are calculated for 400 K and the simulations are perfomed to calculate the vibrational dis- tributions. Thus calculated vibrational distributions at the end of 20 cycles are plotted in the figure 5.12. The ground state (CO2(v0)) density is not shown in the figures as it is always fixed for a given condition. A qualitative description of these distributions is presented here. By including the 20 vibrational states it has been found that there is no difference in CO production from electron induced processes at the end of 20 cycles, which shows that the vibrational kinetics, as described here does not affect the electron energy distribution. However, in reality it will, but since the focus of this chapter is only on theoretical limits to the VV transfer this assumption works in our favor. 1015 1014 1013 1012 1011 1010 10902468101214161820 ν3 Figure 5.12: Vibrational distributions for different pressures and duration of plasma. The total simulation time is 20 cycles at 130 kHz or 0.153 ms. In all the conditions, a vibrational distribution with almost equal number densities 141 1105 ccyycclleess,11000000mm bbaarr 2100 ccyycclleess,,1800000mmbbaarr 1250 ccyycclleess,,880000mm bbaarr 1105 ccyycclleess,,660000mm bbaarr 20cycles600mbar CO2density(/cm3)

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