Understanding CO2 containing non-equilibrium plasmas

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Understanding CO2 containing non-equilibrium plasmas ( understanding-co2-containing-non-equilibrium-plasmas )

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Chapter 6 General Conclusions and Outlook This dissertation deals with several aspects related to plasma assisted CO2 conversion using experiments and modeling. In this part of the thesis, the general conclusions drawn from the work as well as some recommendations for future work are presented. • In the second chapter it has been shown that in a non-equilibrium environment, even in the presence of excited H species, methanation of CO2 proceeds mainly through the formation of CO. Further, the importance of surface is outlined by using copper and aluminum surfaces as examples. For a complete understanding, however, extensive research is required to develop suitable catalysts that work in plasma environment. • The role of atomic O in decreasing production of methane from CO2 by scavenging of H related species has been explained. This insight should be used when new plasma (or non plasma) based CO2 conversion to hydrocarbons is undertaken in the future. • In the third chapter, CO2 dissociation from individual filaments of a dielectric barrier discharge has been described in detail using a pin-pin reactor configura- tion. A simple method of counting filaments using high time-resolution current measurement and corresponding charge transfer along with imaging the filaments has been shown to be useful in understanding the behavior of individual filaments and their contribution to CO production. 147

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