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Working Fluids for Organic Rankine Cycle (ORC) Applications

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Working Fluids for Organic Rankine Cycle (ORC) Applications ( working-fluids-organic-rankine-cycle-orc-applications )

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ICESW IOP Publishing IOP Conf. Series: Materials Science and Enginee1ri2n3g44516378(920‘1’8“)” 012019 doi:10.1088/1757-899X/413/1/012019 indication that condensing temperature does not respond to cost-effective performance and hence, according to Li et al [49], this further corroborates the choice of parameters optimization at a given condensing temperature in many studies. Henrik & Per [50] hence clearly stated that higher critical temperature fluids provide superior performance and are less susceptible to changes in condenser temperature and pressure. Henrik Ö & Per [50] also demonstrated that there is a direct positive correlation between increase in expansion ratio and increased critical temperature of fluids. The fluids with higher critical temperatures showed greater expansion ratio potentials and hence, greater work output potential. They also demonstrated that: (i) fluids with higher critical points offers higher expander enthalpy drop, and consequently greater work output, and (ii) for a fluid expanding between two fixed pressures, the volume expansion ratio decreases with increasing maximum cycle temperature but gives rise to increase in enthalpy drop. Similarly, Wang et al. [40], based their investigation of the performance of ORC systems for WHR solely on the critical temperature criterion, proposed that the critical temperature can be a singular factor for fluid selection. The authors proposed based on their finding that thermal efficiencies have dispersed distribution against every other physical parameter other except for the critical temperature alone. In the investigation, five organic fluids were employed; R245fa, R123, R601, isohexane and hexane, with critical temperatures from low to high. Their results showed correlation between thermal efficiency increase and increase in critical temperature while R601 provided the maximum efficiency because of the closeness between the critical temperature and the heat source temperature. It was in a similar trend discovered by Agromayor & Nord [51] that transcritical-recuperated cycle architecture employing either dry or isentropic organic fluids exhibited optimal performance when the critical temperature of the working fluid was slightly lower than the temperature of the heat source. Conversely, no common relationship was established for the optimal cycle architecture for heat source temperatures higher than the critical temperatures of the organic fluids. Bianchi et al., [52] also reported from studies that specific pumping work reduces as the critical temperature of organic working fluids increases, especially when the critical temperature is greater than 150°C, but no direct relationship with liquid specific heat. 4. Guidelines for Screening of Working Fluids Since the efficiency of the Organic Rankine Cycle for a fixed working condition and the life of the turbine as well significantly depends on the selected dry working fluid [53], it therefore requires an optimization process for the probable working fluids in order to determine the most suitable working fluid in concurrently with the expander selection and the ORC architecture. [42] hence identified thirteen basic guidelines for screening of working fluids highlighted below: • Thermodynamic performance • Positive or isentropic saturation vapor curve • High vapor density • Low viscosity • High conductivity • Acceptable evaporating pressure • Positive condensing gauge pressure • High stability temperature • Melting point • High safety level 5. Conclusion In this study, comprehensive review of working fluids selection for ORC applications has been carried out. Pure and azeotropic fluids have been discussed. The thermo-physical properties, stability, environmental effects, safety and compatibility, and availability and cost which are essential factors to be considered when 9

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