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Resources 2014, 3 161 Figure 2. Example of hydrometallurgical recycling of PCBs for the recovery of PMs [41]. Reproduced with permission from [41], 2009. Table 7. Summary of hydrometallurgical recovery of PMs from e-waste. Investigators Park and Fray [41] Sheng and Estell [49] Quinet et al. [50] Chielewski et al. [51] Zhou et al. [52] Kogan [53] Veit et al. [11] Mecucci and Scott [54] Leaching agent Aqua regia HNO3 (1st stage), epoxy resin (2nd stage), and aqua regia (3rd stage) H2SO4, chloride, thiourea and cyanide leaching HNO3 and aqua regia HCl, H SO and NaClO Process conditions Ratio of metals to leachant = 1:20 g/mL Extraction was carried out in the three stages (self agitation) Leaching & metals recovery by cementation, precipitation, ion exchange and carbon adsorption Roasting of e-waste in the presence of carbon; leaching with HNO3 and aqua regia; and solvent extraction with diethyle malonate Combustion of e-waste at 400–500 °C followed by leaching Dissolution of e-waste in different solvents and leaching conditions; and recovery of metals in stages Mechanical processing and then dissolution of e-waste in different solvents Electrochemical deposition of Cu at cathode from solution Recovered metals Au, Ag and Pd Au Au, Ag, Pd and Cu Au Ag, Au and Pd Al, Sn, Pb and Zn (1st stage), Cu and Ni (2nd stage), Au, Ag, Pd and Pt (last stage) Cu Pb and Cu 2 4 3 HCl, MgCl2, H2SO4 and H2O2 Aqua regia and H2SO4 HNO 3PDF Image | Metal Extraction Processes for Electronic Waste
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