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Table 15. Organic material in produced water from oil operations1 Concentration Range Technique (Method) Constituent TOC COD TSS T otal Oil Volatiles Total Polars Phenols Volatile Fatty Acids Units Low High mg/L ND 1,700 mg/L 1,220 mg/L 1.2 1,000 mg/L 2 565 mg/L 0.39 35 mg/L 9.7 600 mg/L 0.009 23 mg/L 2 4,900 Median NA UV Oxidation/IR (USEPA 415.1) NA Redox Titration (USEPA 410.3) NA Gravimetric (USEPA 160.2) NA Gravimetric (USEPA 413.1) NA GC/MS (USEPA 1624 Rev B and USEPA 24 & CLP) NA Florisil column/IR NA Silylation GLC/MS NA Direct GLC/FID of water 1 ND = below detection limit; NA = not available. Table 16. Volatile organics in produced water from gas operations1 Concentration Range Analytical Method Constituent Benzene Bis (2-chlorethyl) ether Ethylbenzene Phenol T oluene Units Low High mg/L ND 27 mg/L ND 0.03 mg/L ND 19 mg/L ND 2.6 mg/L ND 37 Median Reference Fillo, 1992 GRI report, 1988 GRI report, 1988 GRI report, 1988 Fillo, 1992 GRI report, 1988 2-Butanone 1 ND = below detection limit; NA = not available. NA USEPA Method 1624 and 624 NA NA NA USEPA Method 1624 and 624 NA NA NA USEPA Method 1624 and 624 NA NA mg/L ND 0.37 Produced water from gas production tends to have higher contents of low molecular-weight aromatic hydrocarbons such as benzene, toluene, ethylbenzene, and xylene (BTEX) than water from oil production. Studies indicate that the produced waters discharged from gas/condensate platforms are about 10 times 58PDF Image | Oil and Gas Produced Water Management
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