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Oil and Gas Produced Water Management

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Oil and Gas Produced Water Management ( oil-and-gas-produced-water-management )

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7.2.5.2 Multieffect Distillation In multieffect distillation, vapor from the first evaporator is condensed in the second evaporator and the heat of condensation is used to evaporate the water in the second evaporator. Each evaporator in the series is called an “effect.” 7.2.5.3 Vapor Compression In the vapor compression process, the feed water is preheated in a heat exchanger by the product and reject streams from the process. This process uses a still that contains tubes. The water then is fed to the inside of the tubes, and the vapors then are fed to the outside of the tubes to condense. The gases that do not condense are removed from the steam-condensation space by a vent pump or ejector. The mechanical pump or ejector is a requirement of this process and is necessary to increase the pressure of the vapor to cause condensation. Vapor compression has been used for produced water treatment, and commercially available products currently are marketed for this application. 7.2.5.4 Membrane Distillation Membrane distillation is a thermally driven membrane processes that uses the vapor pressure gradient between the feed solution and the product solution as the driving force. The membrane is hydrophobic and microporous. The flux and salt rejection of this process is independent of feed water salinity. There are many different configurations for the application of membrane distillation. 7.2.6 Alternative Desalination Processes Alternative desalination processes do fall within the thermal or membrane categories and use other materials and mechanisms for desalination. 7.2.6.1 Capacitive Deionization In capacitive deionization, water is passed through pairs of high surface area carbon electrodes that are held at a potential difference of 1.2 volts. Ions and other charged particles are attracted to the oppositely charged electrode. When the electrodes have become saturated with ions, they must be regenerated by removing the applied potential and rinsing the ions out of the system. The carbon aero gel electrodes have a relatively high surface area (500 m2/g) and provide high electrical conductivity, and have a high ion permeability. The electrodes are, however, expensive and have a relatively low ion storage capacity. 7.2.6.3 Softening Softening can be used to remove hardness and silica from the water. Generally, if the water is to be used for agricultural purposes, softening would not be advised because, like nanofiltration, the SAR will be higher following treatment due to removing the divalent ions. 88

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