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Working Fluid Selections in Organic Rankine Cycle ICE

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Working Fluid Selections in Organic Rankine Cycle ICE ( working-fluid-selections-organic-rankine-cycle-ice )

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0.18 0.16 0.14 0.12 0.1 0.08 0.06 0.04 0.02 0 Water Toluene R-245fa R-123 Benzene Pxylene Ethanol R-236ea R-245ca 50 100 150 200 250 300 350 400 Exhaust Gas Temperature (°C) Figure 5. Optimized thermal efficiency against exhaust gas temperature. 35000 30000 25000 20000 15000 10000 5000 0 Water Toluene R-245fa R-123 Benzene Pxylene Ethanol R-236ea R-245ca 50 100 150 200 250 300 350 400 Exhaust Gas Temperature (°C) Figure 6. Optimized work per unit exhaust gas mass flow rate against exhaust gas temperature. As shown by Figure 5, R-123 has larger thermal efficiency over the exhaust temperature range of 80-180 °C. Ethanol has larger thermal efficiency over the exhaust temperature range of 180- 210 °C. Benzene shows larger thermal efficiency at 210-280 °C. Finally, water is the best working fluid at exhaust temperature above 280 °C. Figure 6 shows a similar prediction as Figure 5 with the only difference being that ethanol produces greater amount of work from 180 to 240 °C instead of 210 °C. 15 Work per Unit Exhaust Mass Flow Rate (W/kg) First Law Efficiency ( )

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