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The general shapes of the curves on Figure 11 are very similar to those on Figure 5, while the maximum thermal efficiency that can be reached for each working fluid increases. The “flat” regions on the curves of R-123, R-245fa, R-245ca and R-236ea on Figure 5 disappear on Figure 11, because the efficiency is “free” to increase given the larger pressure limit. An important difference between Figure 11 and Figure 5 is that water gives a higher efficiency starting from 225 °C on Figure 11. Figure 12 is very similar to Figure 6, indicating that work is insensitive to the maximum pressure limit. The reason why only efficiency is sensitive to the maximum pressure limit was explained in section 4.2. 5.2. Minimum pressure limit Minimum pressure (condensing pressure) limit is lowered to 170 kPa with the other assumptions unchanged. Figure 5 and Figure 6 were reproduced as Figure 13 and Figure 14. P-xylene have been removed due to some obviously erroneous data points. Figure 13. First law efficiency assuming minimum pressure limit is 170 kPa. 0.18 0.16 0.14 0.12 0.1 0.08 0.06 0.04 0.02 0 R-123 (Original) Water (Original) Benzene (Original) Ethanol (Original) R-123 Ethanol Benzene Water R-245fa R-236ea R-245ca 50 100 150 200 250 300 350 400 Exhaust Gas Temperature (°C) 21 First Law Efficiency ( )PDF Image | Working Fluid Selections in Organic Rankine Cycle ICE
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