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Nano-Micro Lett. (2022) 14:82 practicalapplicationconditions.Atallconditions,thebatter- ies deliver expected capacity and voltage outputs (Fig. S21). 4 Conclusion In summary, we develop a high performance, low-cost and intrinsically safe rechargeable Zn||I2 aqueous batteries, by means of comprehensively suppressing parasitic reactions on the Zn anodes with a zeolite-based cation-exchange protect- ing layer. On the one hand, the multifunctional zeolite-based layer allows smooth crossover migration of Zn2+, which Zn is deposited uniformly and rapidly. One the other hand, zeolite-based cation-exchange protecting layer can effec- tively block electrolyte and anions from passing through, and effective inhibit dendrite growth, Zn corrosion/passiva- tion, and self-discharge. Thanks to the multifaceted merits of this protecting layer, the resulting Zeolite-Zn||I battery at 0.2 A g−1), a high CE (99.76% in average at 2 A g−1), a long-term cycling stability (91.92% capacity retention after 5600 cycles at 2 A g−1). This work provides a new approach for the achievement of high-performance aqueous Zn||I batteries. Acknowledgements The authors thank the National Natural Science Foundation of China (51502194, 22133005, 21973107, and 22103093), the Natural Science Foundation of Shandong (ZR2020ME024), the Science and Technology Commission of Shanghai Municipality (21ZR1472900), and the Key Laboratory for Palygorskite Science and Applied Technology of Jiangsu Prov- ince (HPK202103) for financial support. Funding Open access funding provided by Shanghai Jiao Tong University. 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Page 11 of 13 82 Supplementary Information The online version contains supplementary material available at https://doi.org/10.1007/ s40820-022-00825-5. References 1. M. Armand, J.M. Tarascon, Building better batteries. Nature 451(7179), 652–657 (2008). https://doi.org/10.1038/451652a 2. M. Li, J. Lu, Cobalt in lithium-ion batteries. Science 367(6481), 979–980 (2020). https://doi.org/10.1126/science. aba9168 3. K. Liu, Y. Liu, D. Lin, A. Pei, Y. Cui, Materials for lithium-ion battery safety. Sci. Adv. 4(6), eaas9820 (2018). https://doi.org/ 10.1126/sciadv.aas9820 4. P.P. Lopes, V.R. Stamenkovic, Past, present, and future of lead-acid batteries. Science 369(6506), 923–924 (2020). https://doi.org/10.1126/science.abd3352 5. B. Dunn, H. Kamath, J.M. Tarascon, Electrical energy stor- age for the grid: a battery of choices. Science 334(6058), 928–935 (2011). https://doi.org/10.1126/science.1212741 6. X. Zeng, J. Hao, Z. Wang, J. Mao, Z. Guo, Recent progress and perspectives on aqueous Zn-based rechargeable batteries with mild aqueous electrolytes. Energy Storage Mater. 20, 410–437 (2019). https://doi.org/10.1016/j.ensm.2019.04.022 7. Y. Liu, X. Lu, F. Lai, T. Liu, P.R. Shearing et al., Recharge- able aqueous Zn-based energy storage devices. Joule 5(11), 2845–2903 (2021). https://doi.org/10.1016/j.joule.2021.10. 011 8. N. Zhang, X. Chen, M. Yu, Z. Niu, F. Cheng et al., Materials chemistry for rechargeable zinc-ion batteries. Chem. Soc. Rev. 49(13), 4203–4219 (2020). https://doi.org/10.1039/ C9CS00349E 9. C. Xu, B. Li, H. Du, F. Kang, Energetic zinc ion chemistry: the rechargeable zinc ion battery. Angew. Chem. Int. Ed. 51(4), 933–935 (2012). https://doi.org/10.1002/anie.20110 6307 10. J. Song, K. Xu, N. Liu, D. Reed, X. Li, Crossroads in the renaissance of rechargeable aqueous zinc batteries. Mater. Today 45, 191–212 (2021). https://doi.org/10.1016/j.mattod. 2020.12.003 11. C.P. Li, X.S. Xie, S.Q. Liang, J. Zhou, Issues and future perspective on zinc metal anode for rechargeable aqueous zinc-ion batteries. Energy Environ. Mater. 3(2), 146–159 (2020). https://doi.org/10.1002/eem2.12067 12. L.E. Blanc, D. Kundu, L.F. Nazar, Scientific challenges for the implementation of Zn-ion batteries. Joule 4(4), 771–799 (2020). https://doi.org/10.1016/j.joule.2020.03.002 13. Z. Zhao, J. Zhao, Z. Hu, J. Li, J. Li et al., Long-life and deeply rechargeable aqueous Zn anodes enabled by a mul- tifunctional brightener-inspired interphase. Energy Envi- ron. Sci. 12(6), 1938–1949 (2019). https://doi.org/10.1039/ C9EE00596J 2−1 simultaneously achieves a high capacity (203–196 mAh g 2 13PDF Image | Boosting Zn Battery by Coating a Zeolite‐Based Cation‐Exchange
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