Synthetic Polymer-based Membrane for Lithium Ion

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Synthetic Polymer-based Membrane for Lithium Ion ( synthetic-polymer-based-membrane-lithium-ion )

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Composite PE Al2O3/PDA ---- ---- 90.1 mAh.g-1 at 5C [127] Blend PE Al2O3/ePOSS/ PVdF-HFP 0.86 ~130 mAh.g-1 at 5C [128] Single PE benzoyl peroxide ---- 0.8 ----- [129] Single PE Graphene oxide coating ---- ---- ---- [130] Composite Glass Fiber MOFs ---- 2.54 2 mAh.cm-2 at 1C [131] Blend PAN/PMMA PDA 56.1 3.61 170.6 mAh.g-1 at 0.2C [132] Single PEEK ---- 84 1.68 154.3 mAh.g-1 [133] To enhance the mechanical properties, thermal and dimensional stabilities, cross-linked membranes covalently integrated with hybrid silsesquioxane components were fabricated by in-situ crosslinking method, obtaining armor-like shell structures coated on PVDF-HFP fibers [107]. This novel cross-linked PVDF-HFP based electrospun membrane shows high porosity and affinity, enhanced mechanical strength, dimensional stability and high lithium ionic conductivity [107]. PVDF-HFP/LLZO composite separators (Figure 5.2) have been developed through the dispersion of LLZO particles into PVDF-HFP polymer matrix, the composite separator with Single PAN ---- 67.26 1.60 117.92 mAh.g-1 at 1C [134] 25

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