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Dense All-Electrochem-Active Electrodes for All-Solid-State Lithium Batteries

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Dense All-Electrochem-Active Electrodes for All-Solid-State Lithium Batteries ( dense-all-electrochem-active-electrodes-all-solid-state-lith )

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www.advancedsciencenews.com www.advmat.de Figure 4. The structure and electrochemical mechanism of the hybrid S–LMS–AEA cathode (32.5%S8–67.5%Mo6S8). a) TEM image of the S–LMS–AEA cathode. b) The cross-sectional SEM images of the AEA cathode/Li10GeP2S12 interface with the energy dispersive spectrometer (EDS) mapping of the P and S elements. c) EDS point analysis of the P and S elements in the AEA cathode (Point 1) and the Li10GeP2S12 (Point 2). The black scale in (a) is 20 nm, and the white scales in (b) and (c) are 50 μm. d,e) Comparison of the electronic conductivities, theoretical volumetric energy density, and porosity of the S–LMS–AEA cathode and those of a typical S–C–LGPS cathode (32.5 wt%, 17.5 wt%, 50 wt%, see the detailed information in Figure S11, Supporting Information). f) The electrochemical redox mechanism of the S–LMS–AEA cathode. Adv. Mater. 2021, 33, 2008723 2008723 (6 of 9) © 2021 Wiley-VCH GmbH

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