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4.3 Nickel electronic structure across the MIT Figure 4.18: Temperature dependent nickel 2p multiplet spectra with fitting for sample S-12AOw - Although the initial room temperature separation of constituent photoelectron lines, it disappears with further temperature treatment Table 4.3: The details of fitting of nickel spectra of S-12AOw sample for various temperatures. The position of fitted peak maximum, area ratio between constituent lines and energy displacement for each temperature are calculated. T,K 1 2 3 7 8 9 1/2 303 855.57 857.22 859.36 872.89 874.85 877.3 0.49 100 851.51 854.60 857.57 872.81 875.97 878.29 0.57 303 854.62 856.09 858.29 872.07 874.04 877.7 0.63 493 853.50 855.00 857.30 871.30 872.7 873.6 0.14 673 853.40 854.80 856.80 871.14 872.4 873.9 0.23 7/8 2-1 8-7 0.39 1.65 1.96 1.89 3.09 3.16 1.16 1.47 1.97 1.86 1.56 1.4 1.01 1.45 1.29 111PDF Image | Investigation of metal-insulator transition in magnetron sputtered samarium nickelate thin films
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