Oxygen Redox Reactions in Batteries Resonant Inelastic X-ray Scattering

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Condens. Matter 2019, 4, 5 12 of 12 15. Qiao, R.; Li, Q.; Zhuo, Z.; Sallis, S.; Fuchs, O.; Blum, M.; Weinhardt, L.; Heske, C.; Pepper, J.; Jones, M.; et al. High-efficiency in situ resonant inelastic X-Ray scattering (iRIXS) endstation at the Advanced Light Source. Rev. Sci. Instrum. 2017, 88, 033106. [CrossRef] [PubMed] 16. Zhuo, Z.; Pemmaraju, C.D.; Vinson, J.; Jia, C.; Moritz, B.; Lee, I.; Sallies, S.; Li, Q.; Wu, J.; Dai, K.; et al. Spectroscopic Signature of Oxidized Oxygen States in Peroxides. J. Phys. Chem. Lett. 2018, 6378–6384. [CrossRef] [PubMed] 17. Dai, K.; Wu, J.; Zhuo, Z.; Li, Q.; Sallis, S.; Hussain, Z.; Liu, G.; Yang, W. High Reversibility of Lattice Oxygen Redox Quantified by Direct Bulk Probes of Both Anionic and Cationic Redox Reactions. Joule 2018, 3, 1–24. [CrossRef] 18. Gent, W.E.; Lim, K.; Liang, Y.; Li, Q.; Barnes, T.; Ahn, S.J.; Stone, K.H.; McIntire, M.; Hong, J.; Song, J.H.; et al. Coupling between oxygen redox and cation migration explains unusual electrochemistry in lithium-rich layered oxides. Nat. Commun. 2017, 8, 2091. [CrossRef] 19. Xu, J.; Sun, M.; Qiao, R.; Renfrew, S.E.; Ma, L.; Wu, T.; Hwang, S.; Nordlund, D.; Su, D.; Amine, K.; et al. Elucidating anionic oxygen activity in lithium-rich layered oxides. Nat. Commun. 2018, 9, 947. [CrossRef] 20. Butorin, S.M.; Guo, J.; Wassdahl, N.; Nordgren, E.J. Tunable-excitation soft X-ray fluorescence spectroscopy of high-Tc superconductors: An inequivalent-site seeing story. J. Electron Spectrosc. Relat. Phenom. 2000, 110–111, 235–273. [CrossRef] 21. Firouzi, A.; Qiao, R.; Motallebi, S.; Valencia, C.W.; Israel, H.S.; Fujimoto, M.; Wray, L.A.; Chuang, Y.D.; Yang, W.; Wessells, C.D. Monovalent manganese based anodes and co-solvent electrolyte for stable low-cost high-rate sodium-ion batteries. Nat. Commun. 2018, 9, 861. [CrossRef] [PubMed] 22. Duda, L.C.; Schmitt, T.; Magnuson, M.; Forsberg, J.; Olsson, A.; Nordgren, J.; Okada, K.; Kotani, A. Resonant Inelastic X-Ray Scattering at the Oxygen K Resonance of NiO: Nonlocal Charge Transfer and Double-Singlet Excitations. Phys. Rev. Lett. 2006, 96, 067402. [CrossRef] [PubMed] 23. Hong, J.; Lim, H.-D.; Lee, M.; Kim, S.-W.; Kim, H.; Oh, S.-T.; Chung, G.-C.; Kang, K. Critical Role of Oxygen Evolved from Layered Li–Excess Metal Oxides in Lithium Rechargeable Batteries. Chem. Mater. 2012, 24, 2692–2697. [CrossRef] 24. Renfrew, S.E.; McCloskey, B.D. Residual Lithium Carbonate Predominantly Accounts for First Cycle CO2 and CO Outgassing of Li-Stoichiometric and Li-Rich Layered Transition-Metal Oxides. J. Am. Chem. Soc. 2017, 139, 17853–17860. [CrossRef] [PubMed] 25. Armstrong, A.R.; Holzapfel, M.; Novák, P.; Johnson, C.S.; Kang, S.-H.; Thackeray, M.M.; Bruce, P.G. Demonstrating Oxygen Loss and Associated Structural Reorganization in the Lithium Battery Cathode Li[Ni0.2Li0.2Mn0.6]O2. J. Am. Chem. Soc. 2006, 128, 8694–8698. [CrossRef] [PubMed] 26. Ament, L.J.P.; van Veenendaal, M.; Devereaux, T.P.; Hill, J.P.; van den Brink, J. Resonant inelastic x-ray scattering studies of elementary excitations. Rev. Modern Phys. 2011, 83, 705–767. [CrossRef] 27. Freelon, B.; Augustsson, A.; Guo, J.H.; Medaglia, P.G.; Tebano, A.; Balestrino, G. Electron correlation and charge transfer in superconducting superlattices. Phys. Rev. Lett. 2006, 96, 017003. [CrossRef] © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).

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