Two-Dimensional Borophene

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Two-Dimensional Borophene ( two-dimensional-borophene )

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12 Research 600 400 200 0 (a) 236 pm 80 100 Lateral distance (nm) (c) 320 pm 160 2 1 0 (b) 1.45 nm 0.5 1.0 1.5 2.0 2.5 Lateral distance (nm) (d) 1.5 nm 60 120 140 0.0 B Al Ag (e) (f) Figure 11: (a) STM image showing a one-atom thick boron island running across an Al(111) step. (c) Line profile corresponding to the black line in (a). (b) The STM image of boron. (d) Line profile corresponding to the green line in (b). (e) Side elevation of honeycomb borophene on Al(111). (f) Side elevation of honeycomb borophene on Ag(111). Reprinted with permission from Ref. [69]. Copyright 2018 Science China Press. rendering the direct exfoliation challenging. Ji et al. synthe- sized the borophene through a top-down approach, which can be divided into two times of liquid exfoliation and one thermal oxidation etching in Figure 13(a) [62]. After the first exfoliation, the B nanosheets appear to be thick. Then, the thick nanosheets can be oxidized to B2O3, which further dis- solves into water. Later, the second ultrasonic exfoliation was employed. Through these three steps, the B nanosheets with Height (nm) Height (pm)

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