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mechanism of triboelectrification and its kinetics, which calls for more experimental evidence to testify existing hypotheses, such as electron transferring by tunneling effect, mass transport, and even a hybrid of both.73 In high vacuum, interfering factors to the triboelectrification such as dust and moisture can be reduced or even eliminated, and a much higher amount of transferred charge can be detected, both of which will favor the evidence seeking process. In practice, our study points out an effective approach for hugely enhancing the output power of TENG, which greatly improves the prospect of large-scale blue energy using nanogenerators networks.60 Considering that existing TENGs proposed for harvesting water wave energy are already enclosed and sealed with waterproof containers,74, 75 it is rather straightforward and cost-effective to make them airtight and keep the inside in vacuum. The resulted boost in electrical output can reduce the size of blue-energy nets, and thus minimize the environmental impacts while meeting the energy needs especially in extreme weather conditions. 2.1.6 Experimental Methods 2.1.6.1 Fabrication of the TENG For the conventional TENG with hard contact taken as the reference, a Cu film (Cu- I) was adhered to an acrylic substrate and acted as an electrode and a triboelectric material simultaneously, while the other triboelectric material, a PTFE film, was adhered to another Cu film (Cu-II) and then onto an acrylic substrate. Its Cu-I, Cu-II and PTFE film were of the same size, 3 ×3 cm2. For the TENG with a cushioned Cu electrode and the fragmental structure, a piece of foam was placed between Cu-I and its corresponding acrylic substrate, 24PDF Image | HIGH PERFORMANCE TRIBOELECTRIC NANOGENERATOR AND ITS APPLICATIONS
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