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HIGH PERFORMANCE TRIBOELECTRIC NANOGENERATOR AND ITS APPLICATIONS

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HIGH PERFORMANCE TRIBOELECTRIC NANOGENERATOR AND ITS APPLICATIONS ( high-performance-triboelectric-nanogenerator-and-its-applica )

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composition of photosensitive agents. The liquid byproducts after degradation can be easily absorbed by soil or paper with minimal residue remaining, which shows its great potential in field application where disposability or stealth is desired. The adjustment of triboelectric property of PPHA film can be explored in future work by surface modification to achieve higher energy conversion efficiency. This work not only broadens the applicability of TENG as transient power sources and sensors, but also expands the use of transient functional polymers towards advanced energy and sensing applications. 2.4.5 Experimental Methods 2.4.5.1 Materials Tetrakis(pentafluorophenyl)borate-4-methylphenyl[4-(1- methylethyl)phenyl]iodonium (PAG) were purchased from TCI Chemicals. Anthracene was purchased from Alfa Aesar. 1-Butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide (BMP TFSI) was purchased from Iolitec. Tetrahydrofuran (THF) was purchased from BDH. All chemicals were used as received. Cyclic PPHA was cationically polymerized using boron trifluoride diethyl etherate (BF3OEt2) as the catalyst at -80 °C following the procedure of Schwartz et al.125 The number-average molecular weight (Mn), weight-average molecular weight (Mw), and polydispersity index (Ð = Mw/Mn) of dried cyclic PPHA was determined by GPC (Shimadzu) equipped with an LC-20 CE HPLC pump and a refractive index detector (RID- 20 A, 120 V), using THF as the solvent. The measured Mn is 355 kg/mol and Ð is 1.26. Nylon (50 μm), PE (100 μm), PET (50 μm) and Kapton (25 μm) films were purchased from McMaster-Carr. Teflon® FEP film (25 μm) was purchased from American Durafilm. 70

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