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Applications of Zeolites in Sustainable Chemistry

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Applications of Zeolites in Sustainable Chemistry ( applications-zeolites-sustainable-chemistry )

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Figure 6. Zeolite/Water-Adsorption Energy Storage System for School Heating During the day, heat was released when water was adsorbed in zeolite X. Water was desorbed at night by district heat, thereby regenerating the adsorption energy storage system. It can be anticipated that with the development of hydrophilic aluminophosphate adsorbents, adsorption energy storage techniques will receive more attention in the near future. Future work includes increasing the stability and recycling life of aluminophosphate zeolites, tuning the performance of zeolites by impregnation with other materials such as hygroscopic salts, and optimizing the technical factors, such as the adsorbent particle size, the design of the adsorption columns, and the operational temperatures, etc., to obtain cost-effective heating. CO2 CAPTURE AND CONVERSION The increase in CO2 concentration in the atmosphere has caused serious environ- mental problems, such as global warming and extreme weather. CO2 emissions mainly come from fossil fuel combustion, which unfortunately is and will continue to be our primary energy source for the next several decades. Many materials have been developed to reduce CO2 emissions, such as activated carbon, metal-organic frameworks, mesoporous silica, metal, and metal oxides, etc., among which zeolites have attracted much attention because of their unique adsorption and catalytic properties. CO2 Capture CO2 capture is a promising strategy to reduce CO2 emissions. Zeolites, along with other porous materials, such as metal-organic frameworks, are among the best inorganic adsorbents for CO2 adsorption. In particular, zeolite frameworks possess strong electric fields, preferentially adsorbing molecules with large dipole and quadruple moments such as CO2. Moreover, various active sites in zeolites as well as their particular porous structures provide a unique shape-selective effect toward 938 Chem 3, 928–949, December 14, 2017

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