Chemical Processes and Use of CO2

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Chemical Processes and Use of CO2 ( chemical-processes-and-use-co2 )

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Chemicals from CO urea synthesis is taken directly from the synthesis gas unit, which is part of the ammonia production process. The urea synthesis reaction is shown in Equation (1): (1) 1.1.2.2.1.2 The Kolbe-Schmitt synthesis of salicylic acid Another example of an established process involving the chemical utilisa- tion of CO2 is the Kolbe-Schmitt reaction (also referred to as the Kolbe pro- cess) in which sodium phenoxide and CO2 react as shown in Equation (2) to form salicylic acid. Salicylic acid can then be reacted further to produce dye- stuffs and odorous compounds. It is also a key component in the manufacture of the active ingredient acetylsalicylic acid, which is more commonly known as AspirinTM. Annual production of salicylic acid is around 70,000 metric tons, for which 25,000 metric tons of CO2 are required. VI The Kolbe Schmitt reaction to form salicylic acid: MOTIVATION, CHALLENGES, OUTLOOK (2) 2 • Acetic acid Urea • Polyurethane foams • Ethylene, Propylene • Polymer precursor • DME • Fuel Methanol • Fertilizer • Resins • Packaging foils/sheets • Preservative • Adhesive • Precursors • Fuel in fuel cells • Surfactants • Food ingredients • Pharmaceuticals • Aspirin • Pesticides • Polymer precursors • Isocyanate precursor • Agrochemicals, • Preservatives, • Cosmetics • Fuel additive • LPG substitute DME Aldehydes • Polymers • Solvents • Dyes • Perfumes • Cosmetic ingredients CO 2 Alcohols • Solvents • Detergents Commercial Demonstration Lab scale • Mineral fillers • Cement/Concrete • Soil stabilisation • Solvents • Electrolytes for Lithium ion batteries • Intermediate for polymer synthesis Inorganic Carbonates Poly(propylene) carbonate Cyclic Carbonates Polycarbonate -etherols Formic Acid Organic Carbonates Organic Acids Salicylic acid Fig. 5: Products from CO2-based syntheses 21

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