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VALERY FUNDED PROJECTS 1.5.4 Exploitation Three patent applications were filed as part of Valery, and four publications have been published in renowned journals such as “Angewandte Chemie”. A large-scale process for the production of valeraldehydes from butane and CO2 is not yet feasible against the background of the state of the art of knowl- edge developed in the project. However, corresponding process syntheses, which can serve as a basis for preliminary planning, are completely available. Particularly with regard to photocatalytic dehydrogenation, it is necessary to identify a catalyst system that catalyses photocatalytic dehydrogenation in sunlight. If such a system exists, a suitable photoreactor must be designed that meets the requirements of photocatalytic dehydration and at the same time plant safety. The hydroformylation process step, on the other hand, has reached such a maturity within the framework of the project that it could be implemented on a large scale. The newly acquired technology platform for ruthenium-based carbonylation will therefore be further investigated and expanded. Since the sustainability of the new process is linked to the photo- chemical step, the process is not yet ready for implementation. 53PDF Image | Chemical Processes and Use of CO2
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