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ECCO2 FUNDED PROJECTS es its maximum at an atomic concentration of copper of about 95 % after which it decreases. Figure 21 shows the results of a DEMS analysis for linear potential curves as a function of copper concentration. The plots show the measured intensities for hydrogen, methane and ethylene. For ease of com- parison, the results for ethylene and methane were also displayed together in a single plot. It can be seen that the ethylene production increases up to a copper concentration of about 90 at% after which it decreases. XRD and SEM analyses demonstrate that this shift is not due to the formation of new phases nor to changes in surface structure. It is presumed that the absorp- tion energies are altered by the presence of a certain amount of cobalt such that the intermediates responsible for the formation of C2 species are bound more effectively. Similar trends were also observed in studies of industrial catalysts. 1.6.4 Exploitation, commercialisation and dissemination of results The electrochemical reduction of CO2 is a promising technology that still requires further development but that fits perfectly into a future renewables- Fig. 21: 3 DEMS Signal for A) H2, B) CH4, C) C2H4, D) CH4+C2H4 as a function of copper concentration and potential 59PDF Image | Chemical Processes and Use of CO2
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