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1CO2 UTILIZATION FFPAG 1.10 FfPaG – Solid and liquid products from gases BMBF Project FKZ 033RC1301 Project Coordinator: Andreas Bode, BASF New Business GmbH Project Partner: TU Dortmund, BASF SE, Linde AG, ThyssenKrupp Industrial Solutions AG, ThyssenKrupp Steel Europe AG, hte GmbH, VDEh-Betriebsforschungszentrum GmbH 1.10.1 Introduction Many raw material resources are in short supply and are becoming even more scarce, energy and raw material prices vary significantly around the world and change with time, and there is increasing focus on reducing global levels of CO2 emissions. In the light of these constraints, companies that compete globally in resource-intensive industries need to develop new process tech- nologies. The FfPaG project shows that cross-sectoral cooperation can lead to the discovery of new approaches and new directions in process technolo- gy and process engineering with the potential to assist the transition to new sources of raw materials, to reduce CO2 emissions, boost CO2 utilisation and drive market competitiveness. Hydrogen, synthesis gas and carbon are and will continue to be major raw materials and basic chemical building blocks for the steel, aluminium, petro- chemical and chemical industries. Hydrogen and carbon dioxide can be converted to synthesis gas, providing an interface to existing petrochemical processes that are used to produce important chemicals, such as methanol, dimethyl ether or Fischer-Tropsch products. However, chemically convert- ing CO2 and hydrogen to syngas will only result in a reduction in CO2 emis- sions if the hydrogen itself can be generated via a low-carbon process. Current methods of achieving low-carbon hydrogen production, e.g. by electrolysing water using electricity from renewable energy sources, are lim- ited by the small size of the plants and the high costs involved. Due to the large quantities of hydrogen required, biomass gasification is also unsuitable as a means of generating low-carbon H2. Other processes are still at an early stager of development [1]. The method of hydrogen production chosen for the FfPaG project was the pyrolysis of methane or natural gas. The pyrolysis reaction is the thermal dis- sociation of methane to hydrogen and solid carbon. Methane pyrolysis has been the subject of study for many decades. The numerous reaction pathways (catalysis, thermal catalysis, plasma) have been examined and the questions 80PDF Image | Chemical Processes and Use of CO2
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