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Chemical Processes and Use of CO2

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Chemical Processes and Use of CO2 ( chemical-processes-and-use-co2 )

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FFPAG FUNDED PROJECTS of CO2 reduction and the different uses for the carbon product have been ad- dressed [2, 3]. Apart from plasma pyrolysis, which yields carbon in the form of soot, the pyrolysis plants currently used are all lab-scale facilities. Plasma py- rolysis is not an option for the FfPaG project as soot is not a suitable raw ma- terial for metallurgical applications, and a number of technical and economic disadvantages would be expected if plasma pyrolysis were used. Benefits of producing carbon by the pyrolysis of methane are that the car- bon product is ash-free and does not contain unwanted components such as alkalis or sulfur- and phosphorus-containing compounds. The fine granular carbon produced is therefore suitable as a replacement for coking coal or for the pulverised coal used in the steelmaking industry. Other possible uses of the solid carbon products are in aluminium smelting and other industri- al sectors. This innovative approach of using solid carbon from natural gas pyrolysis in metallurgical applications requires inter-sector collaboration in both research and the subsequent commercialisation of the results. 1.10.2 Project description The aim of the project is to develop a pilot plant concept for a new type of production process in which solid and liquid products are formed from Fig. 28: Overview of the FfPaG project and its constituent stages: methane pyrolysis, catalytic CO2 activation by the reverse water-gas shift reaction (RWGS), and the production and control of the granular carbon (upper photo: Linde AG; lower photo: Anodes, Dubal smelter, Dubai UAE, Source: International Aluminium Institute – by kind permission of Emirates Global Aluminium) 81

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