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Chemical Processes and Use of CO2

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Chemical Processes and Use of CO2 ( chemical-processes-and-use-co2 )

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1CO2 UTILIZATION ACER 1.13.2 Project description The planned project showed a high degree of scientific and technical com- plexity, which is why the work was carried out in a three-year joint project with the project partners BASF SE, hte AG, Catalysis Research Laboratory (CaRLa), University of Stuttgart (AK Klemm) and TU Munich (AK Rieger). The task of the CaRLa, which is operated by BASF SE and the University of Heidelberg, as well as the Rieger Group at the Technical University of Mu- nich, was to carry out basic research into the development of catalytic re- action control, starting with investigations into the understanding of the mechanism, through spectroscopic characterisation under reaction condi- tions, to the preparative synthesis of model catalysts for homogeneous re- action control. The testing of a large number of promising homogeneous and heterogene- ous catalysts was the task of hte. While the preparation of the heterogene- ous catalyst candidates was carried out exclusively by hte, the homogeneous catalyst candidates were also provided and tested by the project partners TU Munich and BASF/CaRLa. In the group “Klemm” at the University of Stuttgart, work was carried out on modelling the phase behaviour, the individual process stages and the overall process. This supported the process design. Furthermore, the individual pro- cess steps such as reaction, reprocessing and purification were investigated experimentally using model systems. In the CaRLa Catalyst Laboratory, BASF has examined its own and the model catalysts provided by the Technical University of Munich for their suitability from an industrial point of view and has tested various reaction control variants, found independent catalyst systems and studied their mode of ac- tion. Furthermore, the individual process steps such as reaction, reprocess- ing and purification were investigated experimentally using model systems. All project partners have regularly exchanged ideas and opinions on a large team or bilaterally. hte has made resources available to all project partners, especially BASF/CaRLa, for catalyst testing and evaluation. The TUM has investigated kinetics with CaRLa ligand systems. Furthermore, samples of CaRLa and hte were regularly examined at the University of Stuttgart. BASF/ CaRLa and TUM have provided analytical resources to all project partners (NMR, in situ IR, HPLC). In addition, BASF/CaRLa supported the work pack- ages of all project partners, especially hte’s work packages with quantum mechanical calculations. 102

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