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2 CHEMICAL ENERGY STORAGE SUNFIRE Fig. 64: Power-to-liquid process 2 3 4 5 1. In the HTE stage, electrical energy is used to generate H2 from steam: H2O => H2 + 0.5 O2 2. CO2 and H2 are mixed in a ratio of 1:3 and then heated to a temperature of approxi- mately 1000 °C by an electrical heater: CO2 + 3 H2 3. In the conversion reactor, the mildly endothermic reverse water-gas shift reaction reduces CO2 on a nickel catalyst to CO (synthesis gas): CO2 + 3 H2 => CO + 2 H2 + H2O 4. The hot syngas from the conversion reactor enters the recuperators where in a counter-flow configuration it cools by pre-heating fresh CO2 and steam. 5. The cooled syngas then undergoes a catalysed exothermic reaction in the synthesis reactor at a temperature of between about 200–300 °C (depending on the synthesis being carried out) to produce a liquid fuel: CO + 2 H2 + H2O => - CH2- + 2 H2O The energy released during the synthesis stage is used to vaporise fresh water in the steam-cooled synthesis reactor. The steam is then superheated (see step 4) for use in electrolysis. 1 136 SYNGAS SYNGAS H2O-STEAM H2O-STEAMPDF Image | Chemical Processes and Use of CO2
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