Chemical Processes and Use of CO2

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Chemical Processes and Use of CO2 ( chemical-processes-and-use-co2 )

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2 CHEMICAL ENERGY STORAGE SEE Fig. 70: The SEE process chain indicating the six project work packages The stored SNG could then be used in a range of industrial sectors whenever and wherever demand arose. For example, the gas could be used to power CHP units to regenerate electricity or it could be transferred to the indust- rial, chemical, heating or transport sectors where it could be used to reduce emissions of anthropogenic carbon. 2.4.2 Project description The project examined the entire power-to-gas process chain, beginning wi- th the fluctuating supply of excess electricity, the high-pressure electrolysis of water, CO2 methanation via a novel 3-phase reactor concept, and adjust- ment of calorific value based on a Fischer-Tropsch synthesis involving H2 and CO2. The main focus was on process development and optimisation to accommo- date the dynamic operation of the process chain. It was also a project objective that raw materials for both the main and se- condary processes would be supplied entirely from renewable sources. A total of six work packages were defined in which all of the sub-proces- ses were studied in detail and developed. Potential synergies between the individual process stages were identified and assessed from both a systems analysis and an economic perspective (see Fig. 70). The project consortium comprised three research institutions and four industrial partners. Overall project coordination was performed by the DVGW Research Centre at the Engler Bunte Institute in Karlsruhe. el. energy dynamic Electrolysis WP 2, 3 Methanation – in ionic liquids or – Horden-reactor Calorific value adjustment Fischer-Tropsch- Synthesis WP 4 WP 5: System view Heat energy dynamic or stationary Natural gas network PEM dynamic H2-storage (optional) WP 1 CO -source 2 Biogas plant, gasification, chemical plant Heat energy WP 6: Profitability analysis 150

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