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3 ENERGY-EFFICIENT PROCESSES Fig. 84: Temperature profile of the solvent stream in the absorber tower Process temperatures must be specified and set in such a way that the overall water balance in the system is maintained. Furthermore, the upper limit of the temperature range is determined by the drop in CO2 loading with in- creasing temperature, while the lower limit is dictated by the slower reaction rate at lower temperatures. Temperatures in the desorber tower The maximum temperature that can be achieved in the desorber is deter- mined by the pressure and the boiling points of the low-boiling compo- nents. To speed up solvent regeneration by increasing the rate of CO2 deso- rption (stripping), the position of chemical equilibrium has to be shifted by increasing the temperature and pressure in the tower. However, increasing temperature and pressure causes greater levels of solvent degradation and corrosion. PCC processes involving aqueous amine solutions typically have desorber pressures in the range 1–3 bar and temperatures at the base of the desorber column of 120–135 °C. Flue gas outlet Detergent inlet Separation efficiency per segment [%] Flue gas intlet Detergent outlet Detergent temperature [°C] Separation efficiency per segment Detergent temperature 90% CO2- capture 194PDF Image | Chemical Processes and Use of CO2
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