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CO2 Separation with Ionic Liquids

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CO2 Separation with Ionic Liquids ( co2-separation-with-ionic-liquids )

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Figure 11. Effect of pressure in flash tank on (a) YCH4,PG and loss ratio of CH4; (b) Energy utilization and RECO2 using 50 wt. % ChCl/Urea (1:2) as absorbent The flash tank was used to minimize the methane loss, and the pressure of the flash tank (pflash) affected YCH4,PG, RECO2, the loss ratio of methane and the total energy utilization. Based on values of Nab and L/G listed in Table 6, the sensitivity analysis was further conducted on pflash. Results for different aqueous ChCl/Urea (1:2) solutions are similar, and Figure 11 illustrates the results for 50 wt. % ChCl/Urea (1:2) as one example. As shown in Figure 11, when pflash was higher than 0.3 MPa, YCH4,PG, RECO2 and the total energy utilization almost maintained as constants, but the loss ratio of methane increased greatly. To maintain the loss of CH4 lower than 1 %, pflash should be in a range of 0.3 - 0.34 MPa using 50 wt. % ChCl/Urea (1:2) as absorbent. While for water, 30 wt. % ChCl/Urea (1:2), and 70 wt. % ChCl/Urea (1:2), the ranges were 0.3 MPa ≤ pflash ≤ 0.36 MPa, 0.3 MPa ≤ pflash ≤ 0.35 MPa and 0.3 MPa ≤ pflash ≤ 0.31 MPa, respectively. Based on the analysis, it was proper to set pflash to be 0.3 MPa for all of these absorbents in order to achieve the target of the loss of methane (<1%). In desorption, the ratio of the air flow rate to that of biogas (AFR/G, m3∙m-3) affected the desorption rate of CO2 (ηCO2), YCH4,PG, YCH4,SG and the total energy utilization. The ηCO2 was defined as the mole flow rate of CO2 in the off gas left from the desorber divided the mole flow rate of CO2 in the rich solvent entered into the absorber. Based on the optimal Nab, L/G and pflash for each solvent, the effect of AFR/G on the process performance was studied. In general, with the increase of AFR/G, YCH4,PG, ηCO2 and YCH4,SG changed dramatically at first and then slightly when AFR/G was higher than 2.1 as shown in Figure 12. While the total energy utilization increased linearly with the increase of AFR/G. Meanwhile, the concentration of ChCl/Urea (1:2) did not show an obvious influence on the optimal AFR/G. Therefore, the AFR/G was set to be 2.1 for all of these absorbents in order to achieve the target of the methane purity in product. The final results are listed in Table 6. As we can see from Table 6, when AFR/G was set to be 2.1 for these absorbents, ηCO2 changed slightly when the content of ChCl/Urea (1:2) was changed from 0 to 50 wt. %. While for 70 wt. % ChCl/Urea (1:2), the ηCO2 changed greatly compared with other solvents due to the difficulty to desorb CO2. 17

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