Continuous Valorization of Glycerol into Solketal

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Continuous Valorization of Glycerol into Solketal ( continuous-valorization-glycerol-into-solketal )

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Sustain. Chem. 2021, 2 317 First Inventor, Publication Date Yujia, 2020 Yujia, 2020 Patent CN111253363A CN111253362A CN111253364A Assignee China Petroleum & Chemical Corporation China Petroleum & Chemical Corporation Nippon Oil & Fat Co. Ltd. Christof International Management GmbH Eastman Chemical Co Rhodia Operations SAS Rhodia Poliamida e Especialidades Ltd.a Rhodia Poliamida e Especialidades Ltd.a Eastman Chemical Co Eastman Chemical Co Institute of Biochemical Physics, Russian Academy of Sciences, in association with Company Tatneft Table 5. Cont. Catalyst Heterogeneous catalyst Heterogeneous catalyst Homogeneous catalyst Heterogeneous catalyst Homogeneous catalyst Homo- or heterogeneous Homogeneous catalyst Homogeneous catalyst Heterogeneous catalyst Heterogeneous catalyst Homogeneous catalyst Reaction Tank, fixed bed, moving bed, suspended bed, or slurry bed reactor with a mixture of a titanium silicalite and a tin silicalite molecular sieves Tank, fixed bed, moving bed, suspended bed, or slurry bed reactor with tin-silicon molecular sieve Reactor with stirring equipment Plug-flow reactor Reaction vessel Reaction vessel or fixed-bed reactor Reaction vessel Reaction vessel Fixed-bed reactor Fixed-bed reactor Reaction vessel Separation Not specified Not specified Distillation column(s) Distillation column(s) Distillation column(s) Distillation column(s) Decantation, filtration, or centrifugation, followed by liquid-liquid extraction and distillation(s) Distillation column(s) Distillation column(s) Distillation column(s) Distillation column(s) Ref [134] [135, 136] [137] [138] [139] [140] [141] [142] [143] [144] [145] Traditonal production methods Abe, 2004 Wimmer, 2011 Terrill, 2012 Mastroianni, 2013 Rodrigues, 2013 Rodrigues, 2014 Terrill, 2014 Terrill, 2016 Varfolomeev, 2018 JP2006273750A EP2183238A1 US20120330033A1 US20130178638A1 WO2013045967A1 US20140235878A1 US8829206B2 US9440944B2 RU2625318C2 Evidencing the industrial applicability of reactive distillation as a PI strategy, BASF SA and Guangzhou Yintian New Material Co. proposed new methods for producing

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