PDF Publication Title:
Text from PDF Page: 008
Materials 2021, 14, 1786 8 of 20 Table 3. Geometric information (distances in Å and angles in degrees) for the D–H···O hydrogen bond interactions of SmCP1, {[Sm(Haip)(aip)(H2O)5]·4(H2O)}n, and TbCP1, {[Tb(Haip)(aip)(H2O)5]·4(H2O)}n, crystal structures. D–H···O O1W–H1W···O5Wiii O1W–H2W···O2 O2W–H3W···O9iv O2W–H4W···O7i O3W–H5W···O4i O3W–H6W···O8Wiv O4W–H7W···O8W O4W–H8W···O8v O5W–H9W···O7v O5W–H10W···O9W O6W–H11W···O8 O6W–H11W···O7Wvi O6W–H12W···O4 O7W–H14W···O3W O8W–H15W···O5 N1–H1···O6vii N1–H2···O6Wvii N1–H3···O2vii N2–H10···O6vii O8W–H16W···O6Wviii O9W–H17W···O7vi O9W–H18W···O5 O9W–H18W···O6 N2–H9···O7W SmCP1 d (H···O) 1.927(2) 1.814(2) 1.86(2) 1.99(2) 1.82(2) 1.837(2) 1.870(2) 1.706(2) 1.80(2) 1.83(2) 2.49(3) 2.13(2) 1.840(2) 1.88(2) 2.21(3) 1.96(2) 1.920(2) 1.95(2) 2.55(3) 1.92(2) 1.881(2) 2.56(3) 1.865(2) 2.28(3) d (D···O) 2.801(3) 2.669(3) 2.738(3) 2.846(3) 2.675(3) 2.722(3) 2.745(3) 2.603(3) 2.669(3) 2.693(3) 3.021(3) 2.951(4) 2.712(4) 2.809(4) 2.961(3) 2.808(4) 2.797(4) 2.784(4) 3.174(4) 2.777(4) 2.755(3) 3.130(3) 2.742(3) 3.041(4) ∠ (DHO) 173(3) 163(3) 172(3) 161(3) 160(4) 175(4) 179(4) 178(4) 169(3) 167(3) 120(3) 155(3) 171(4) 171(4) 146(3) 162(3) 176(3) 158(3) 130(3) 162(4) 170(3) 123(3) 172(3) 147(3) D–H···O O1W–H1W···O6 O1W–H2W···O9W O2W–H3W···O4iii O2W–H4W···O9Wiv O3W–H5W···O3iii O3W–H6W···O6W O4W–H7W···O6Wvi O4W–H8W···O3ii O5W–H9W···O7i O5W–H10W···O3Wvii O6W–H11W···O1 O6W–H11W···O2 O6W–H12W···O3v O7W–H13W···O1W O7W–H14W···O6x O9W–H17W···O1vi O9W–H18W···O8W O8W–H15W···O4ix O8W–H15W···O7W O8W–H16W···O6x N1–H1···O7W N1–H2···O2ix N2–H2A···O7vii N2–H2B···O8Wii TbCP1 d (H···O) 1.81(3) 1.84(2) 1.71(3) 1.86(2) 1.80(3) 1.82(3) 1.90(4) 2.04(4) 1.79(2) 1.92(2) 2.60(5) 1.83(2) 1.90(3) 1.93(2) 2.47(4) 2.12(4) 1.95(3) 2.59(9) 2.28(9) 1.90(8) 2.34(4) 2.54(7) 2.10 2.26 d (D···O) 2.662(6) 2.708(7) 2.603(7) 2.762(8) 2.677(7) 2.695(7) 2.726(7) 2.846(7) 2.661(6) 2.807(7) 3.124(7) 2.722(6) 2.757(6) 2.833(8) 3.271(9) 2.983(7) 2.790(8) 3.025(8) 2.922(9) 2.707(8) 3.048(9) 3.183(8) 2.776(7) 2.799(8) ∠ (DHO) 156(7) 170(6) 167(7) 178(6) 165(6) 161(6) 153(7) 149(7) 165(6) 170(6) 117(4) 167(6) 159(7) 169(8) 146(7) 160(7) 155(7) 124(9) 156(11) 172(8) 149(7) 143(7) 130 117 Symmetry transformations used to generate equivalent atoms: SmCP1 data: (i) −x+3/2, y−1/2, −z+3/2; (ii) −x+3/2, y+1/2, −z+3/2; (iii) −x+1, −y, −z+1; (iv) x+1, y, z; (v) −x+1/2, y−1/2, −z+3/2; (vi) x−1/2, −y+1/2, z−1/2; (vii) x+1/2, −y+1/2, z+1/2; TbCP1 data: (i) −x+3/2, y−1/2, −z+3/2; (ii) −x+3/2, y+1/2, −z+3/2; (iii) −x+5/2, y+1/2, −z+3/2; (iv) x+1, y, z; (v) x+1/2, −y+1/2, z+1/2; (vi) x−1, y, z; (vii) −x+2, −y+1, −z+2; (viii) −x+2, −y+1, −z+1; (ix) x−1/2, −y+1/2, z −1/2; (x) −x+1, −y+1, −z+1. The crystal structure of TbCP2 was determined in the monoclinic system, with space group P21/c, and revealed a 2D CP (coordination layered material) with general formula {[Tb(Haip)(aip)(H2O)2]·H2O}n. Comparatively to the previous CPs, SmCP1 and TbCP1, {[Tb(Haip)(aip)(H2O)5]·4H2O}n, this one revealed a significant decrease in the coordinated and uncoordinated water molecules: a total diminution of seven water molecules is verified. Furthermore, small variation in the reactant’s ratio led to a dimensionality increase: 1D for TbCP1 to 2D for TbCP2. The complete coordination environment for Tb center in the crystal structures of TbCP2 is shown in Figure 3a, being nine-coordinated {TbO9} and presents a geometry closer to a distorted mono-capped square antiprismatic (Figure 3b). Tb–O bond lengths were found between 2.290(3) Å and 2.661(3) Å, while the O–Tb–O angles ranged from 51.46(9)◦ to 155.01(10)◦ (more detailed information can be obtained in Table S3 of the Supplementary Material).PDF Image | Green Chemistry with Supercritical CO2 and Enzymes
PDF Search Title:
Green Chemistry with Supercritical CO2 and EnzymesOriginal File Name Searched:
materials-14-01786.pdfDIY PDF Search: Google It | Yahoo | Bing
NFT (Non Fungible Token): Buy our tech, design, development or system NFT and become part of our tech NFT network... More Info
IT XR Project Redstone NFT Available for Sale: NFT for high tech turbine design with one part 3D printed counter-rotating energy turbine. Be part of the future with this NFT. Can be bought and sold but only one design NFT exists. Royalties go to the developer (Infinity) to keep enhancing design and applications... More Info
Infinity Turbine IT XR Project Redstone Design: NFT for sale... NFT for high tech turbine design with one part 3D printed counter-rotating energy turbine. Includes all rights to this turbine design, including license for Fluid Handling Block I and II for the turbine assembly and housing. The NFT includes the blueprints (cad/cam), revenue streams, and all future development of the IT XR Project Redstone... More Info
Infinity Turbine ROT Radial Outflow Turbine 24 Design and Worldwide Rights: NFT for sale... NFT for the ROT 24 energy turbine. Be part of the future with this NFT. This design can be bought and sold but only one design NFT exists. You may manufacture the unit, or get the revenues from its sale from Infinity Turbine. Royalties go to the developer (Infinity) to keep enhancing design and applications... More Info
Infinity Supercritical CO2 10 Liter Extractor Design and Worldwide Rights: The Infinity Supercritical 10L CO2 extractor is for botanical oil extraction, which is rich in terpenes and can produce shelf ready full spectrum oil. With over 5 years of development, this industry leader mature extractor machine has been sold since 2015 and is part of many profitable businesses. The process can also be used for electrowinning, e-waste recycling, and lithium battery recycling, gold mining electronic wastes, precious metals. CO2 can also be used in a reverse fuel cell with nafion to make a gas-to-liquids fuel, such as methanol, ethanol and butanol or ethylene. Supercritical CO2 has also been used for treating nafion to make it more effective catalyst. This NFT is for the purchase of worldwide rights which includes the design. More Info
NFT (Non Fungible Token): Buy our tech, design, development or system NFT and become part of our tech NFT network... More Info
Infinity Turbine Products: Special for this month, any plans are $10,000 for complete Cad/Cam blueprints. License is for one build. Try before you buy a production license. May pay by Bitcoin or other Crypto. Products Page... More Info
| CONTACT TEL: 608-238-6001 Email: greg@infinityturbine.com | RSS | AMP |