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Section 1 Water splitting and sustainable H2 production Alexis Grimaud (CNRS – Colle`ge de France) Jan Rossmeisl (University of Copenhagen) Peter Strasser (Technical University Berlin) 1.1 Importance of subject Securing the provision of the required energy and materials to a growing number of people on Earth with minimal environmental impact requires the sustainable production of fuels and chemicals. This implies closing the technological cycles of key elements such as carbon, nitrogen, hydrogen, and oxygen. Closing the hydrogen cycle through large-scale production of molecular hydrogen is of particular importance to provide the required chemically reducing equivalents to close the other cycles, particularly the carbon cycle. Hydrogen itself is an energy storage molecule and reactive chemical intermediate that enables a large variety of indispensable chemical transformations to more complex energy storage molecules or industrial chemicals and materials (see Sections 3, 4, and 5). Under the premise of the availability of cheap renewable electricity, the electrolytic production of hydrogen from water is an attractive route. While the earth’s surface water is technically not the only possible feedstock for this process, it is the best choice since its global abundance is commensurate with the scale of hydrogen required for the sustainable production of fuels and chemicals. Electrolytic hydrogen production and its various uses are key enablers of a new type of energy and chemical industry system, characterized by a close coupling of previously separate technology sectors such as transport, chemicals, electricity, and energy storage. Distributed production of hydrogen is potentially useful for the refueling of light, medium, and heavy road vehicles; trains; 10PDF Image | sustainable production of fuels and chemicals
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