sustainable production of fuels and chemicals

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Figure 2.2: Role of CO2RR in the grand scheme of sustainable fuels and chemicals. (Section 4), water electrolysis (Section 1), CO2 capture (Section 10), bio-inspired catalysis (Section 7), and homogeneous catalysis (Section 6). 2.2 State of the art and scientific challenges The most common CO2RR products are two-electron products, namely CO and formic acid, and can be generated by several molecular and heterogeneous catalysts (e.g. silver for CO production) at high rates and faradaic efficiencies. CO is a particularly important target product for the chemical industry, as it is widely employed in several large-scale industrial processes, such as the Fischer-Tropsch synthesis of liquid fuels, the production of methanol, the Monsanto/Cativa acetic acid synthesis, and the hydroformylation of olefins to aldehydes and alcohols (see Sections 3, 4, and 6). Moreover, electrochemical CO2-to-CO has also attracted growing interest for applications in organic synthesis, where CO produced in situ may be used for a wide variety of carbonylation reactions [2]. The formation of further reduced products, such as multicarbon alcohols and hydrocarbons (C2+), is even more attractive due to their higher energy content and importance as chemical feedstocks. Ethylene is a particularly attractive target molecule since it is essential for the industrial production of plastics, detergents, and agricultural products, and state of the art systems have demonstrated impressive energy efficiency and reaction rates for ethylene production, but long-term stability needs to be significantly improved. Copper-based heterogeneous materials are the only catalysts reported so far that can catalyze the electrochemical conversion of CO2 to C2 hydrocarbons and oxygenates with non-negligible selectivity. However, the selectivity is still too low and the overpotential too high for practical applications. In addition, the catalyst surface has been shown 20

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