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7A. A ́lvarez, A. Bansode, A. Urakawa, A. V. Bavykina, T. A. Wezendonk, M. Makkee, J. Gascon, and F. Kapteijn, “Challenges in the greener production of formates/formic acid, methanol, and DME by hetero- geneously catalyzed CO2 hydrogenation processes”, Chemical Reviews, 117, 9804–9838 (2017). 8H. Bahruji, M. Bowker, W. Jones, J. Hayward, J. R. Esquius, D. Morgan, and G. Hutchings, “PdZn catalysts for CO2 hydrogenation to methanol using chemical vapour impregnation (CVI)”, Faraday Dis- cussions, 197, 309–324 (2017). 9F. Studt, I. Sharafutdinov, F. Abild-Pedersen, C. F. Elkjær, J. S. Hummelshøj, S. Dahl, I. Chorkendorff, and J. K. Nørskov, “Discovery of a Ni-Ga catalyst for carbon dioxide reduction to methanol”, Nature Chemistry, 6, 320 (2014). 10G. Prieto, “Carbon dioxide hydrogenation into higher hydrocarbons and oxygenates: Thermodynamic and kinetic bounds and progress with heterogeneous and homogeneous catalysis”, ChemSusChem, 10, 1056– 1070 (2017). 11H. M. T. Galvis, J. H. Bitter, C. B. Khare, M. Ruitenbeek, A. I. Dugulan, and K. P. de Jong, “Supported iron nanoparticles as catalysts for sustainable production of lower olefins”, Science, 335, 835–838 (2012). 12J. Anton, J. Nebel, H. Song, C. Froese, P. Weide, H. Ruland, M. Muhler, and S. Kaluza, “The effect of sodium on the structure–activity relationships of cobalt-modified Cu/ZnO/Al2O3 catalysts applied in the hydrogenation of carbon monoxide to higher alcohols”, Journal of Catalysis, 335, 175–186 (2016). 13O.-S. Joo, K.-D. Jung, I. Moon, A. Y. Rozovskii, G. I. Lin, S.-H. Han, and S.-J. Uhm, “Carbon dioxide hydrogenation to form methanol via a reverse-water-gas-shift reaction (the CAMERE process)”, Industrial & Engineering Chemistry Research, 38, 1808–1812 (1999). 14S. M. Kim, P. M. Abdala, T. Margossian, D. Hosseini, L. Foppa, A. Armutlulu, W. van Beek, A. Comas- Vives, C. Cop ́eret, and C. Mu ̈ller, “Cooperativity and dynamics increase the performance of NiFe dry reforming catalysts”, Journal of the American Chemical Society, 139, 1937–1949 (2017). 15L. C. Buelens, V. V. Galvita, H. Poelman, C. Detavernier, and G. B. Marin, “Super-dry reforming of methane intensifies CO2 utilization via Le Chatelier’s principle”, Science, 354, 449–452 (2016). 16M. Bailera, P. Lisbona, L. M. Romeo, and S. Espatolero, “Power to Gas projects review: Lab, pilot and demo plants for storing renewable energy and CO2”, Renewable and Sustainable Energy Reviews, 69, 292– 312 (2017). 17B. Mutz, H. W. Carvalho, S. Mangold, W. Kleist, and J.-D. Grunwaldt, “Methanation of CO2: Structural response of a Ni-based catalyst under fluctuating reaction conditions unraveled by operando spectroscopy”, Journal of Catalysis, 327, 48–53 (2015). 18L. Hu and A. Urakawa, “Continuous CO2 capture and reduction in one process: CO2 methanation over unpromoted and promoted Ni/ZrO2”, Journal of CO2 Utilization, 25, 323–329 (2018). 19I. Champon, A. Bengaouer, A. Chaise, S. Thomas, and A.-C. Roger, “Carbon dioxide methanation kinetic model on a commercial Ni/Al2O3 catalyst”, Journal of CO2 Utilization, 34, 256–265 (2019). 20Q. Liu, L. Wu, R. Jackstell, and M. Beller, “Using carbon dioxide as a building block in organic synthesis”, Nature Communications, 6, 5933 (2015). 37

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