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into value-added chemicals. The lighthouse project exemplified in Figure 6.3 provides an illustra- tive example of an immediately possible fossil-free development. However, the long-term success of the transition to renewables will rely on new and disruptive approaches for accelerating catalyst development and designing catalytic processes from the molecular to the system level. Ultimately, this will lead to novel technologies that directly utilize electrons and photons to drive chemical transformations of renewable feedstocks via novel pathways, thus providing a new paradigm in the chemical industry. The scientific challenges and goals outlined in this report will require co- ordinated efforts of interdisciplinary teams involving academic and industrial partnerships at the international level. References 1B. Cornils, W. A. Herrmann, M. Beller, and R. Paciello, Applied Homogeneous Catalysis with Organometal- lic Compounds: A Comprehensive Handbook in Four Volumes, Vol. 4 (John Wiley & Sons, 2017). 2Chemistry for Europe, https://cefic.org/app/uploads/2019/07/Chemistry-for-Europe.pdf, Accessed: 2019-07-03. 3P. W. Van Leeuwen, Homogeneous catalysis: understanding the art (Springer Science & Business Media, 2006). 4A. Le Goff, V. Artero, B. Jousselme, P. D. Tran, N. Guillet, R. M ́etay ́e, A. Fihri, S. Palacin, and M. Fontecave, “From hydrogenases to noble metal–free catalytic nanomaterials for H2 production and uptake”, Science, 326, 1384–1387 (2009). 5J. Artz, T. E. Mu ̈ller, K. Thenert, J. Kleinekorte, R. Meys, A. Sternberg, A. Bardow, and W. Leitner, “Sustainable conversion of carbon dioxide: an integrated review of catalysis and life cycle assessment”, Chemical Reviews, 118, 434–504 (2017). 6A. Tlili, E. Blondiaux, X. Frogneux, and T. Cantat, “Reductive functionalization of CO2 with amines: an entry to formamide, formamidine and methylamine derivatives”, Green Chemistry, 17, 157–168 (2015). 7K. Beydoun, K. Thenert, E. S. Streng, S. Brosinski, W. Leitner, and J. Klankermayer, “Selective Synthesis of Trimethylamine by Catalytic N-Methylation of Ammonia and Ammonium Chloride by utilizing Carbon Dioxide and Molecular Hydrogen”, ChemCatChem, 8, 135–138 (2016). 8Q. Liu, L. Wu, R. Jackstell, and M. Beller, “Using carbon dioxide as a building block in organic synthesis”, Nature Communications, 6, 5933 (2015). 9S. Deutz, D. Bongartz, B. Heuser, A. K ̈atelh ̈on, L. Schulze Langenhorst, A. Omari, M. Walters, J. Klanker- mayer, W. Leitner, A. Mitsos, S. Pischinger, and A. Bardow, “Cleaner production of cleaner fuels: wind- to-wheel – environmental assessment of CO2-based oxymethylene ether as a drop-in fuel”, Energy & En- vironmental Science, 11, 331–343 (2018). 10L. E. Heim, H. Konnerth, and M. H. Prechtl, “Future perspectives for formaldehyde: pathways for reductive synthesis and energy storage”, Green Chemistry, 19, 2347–2355 (2017). 67PDF Image | sustainable production of fuels and chemicals
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