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TYPICAL INITIAL OUTPUT OF A CO2 HEAT PUMP

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TYPICAL INITIAL OUTPUT OF A CO2 HEAT PUMP ( typical-initial-output-co2-heat-pump )

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Unlike other convectional refrigerants, CO2 has a very low critical temperature (see table 1). This makes it difficult for use in a sub-critical (convectional) cycle where typical condensing temperatures range between 80-110 °C. In a sub-critical cycle, a low critical temperature is a disadvantage because it limits the operating temperature range; heat cannot be delivered at temperatures greater than the critical temperature. Further, at temperatures less than but near critical temperature, the enthalpy of vaporization is reduced. This leads to a reduction in heating capacity and poor performance of the system. Therefore, for low critical temperature refrigerants, a trans-critical heat pump cycle would perform better than a sub-critical cycle. In a trans-critical heat pump, heat rejection pressures are greater than the critical pressure and heat delivery temperatures are no longer limited by critical temperature. Heat rejection occurs by single-phase sensible cooling (gas cooling) and thus takes place via a gas cooler rather than a condenser. A typical trans-critical cycle is depicted in a temperature-entropy (T-S) diagram as shown in figure 1. The process is characterized by isentropic compression (process 1-2), isobaric heat output (2-3), isenthalpic expansion (3-4) and isobaric heat intake (4-1). Figure 1: Theoretical trans-critical cycle. This cycle is advantageous in some application such as domestic water heating (DHW) where it is possible to maintain a low temperature difference between the refrigerant and the heated fluid in the high-pressure side heat exchanger, in comparison with refrigerants that function within the sub-critical regime [6]. This is possible because in the supercritical state, the vapor–liquid state does not exist and the refrigerant temperature constantly changes in the high-pressure side heat exchanger. Since the gas cooler rejects heat by sensible cooling, the difference between the inlet and outlet temperatures (temperature glide) is much greater than in a condensing process. Thus the trans-critical cycle is more beneficial for heating applications requiring large temperature increase. The CO2 heat pump water heater has the capability of supplying high-temperature DHW, which eliminates the requirement for supplementary heating. This is made possible because of the high energy efficiency of the 318

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