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Energies 2010, 3 1518 Fuel/oxidant 2 M EG, 4 M NaOH /O2 0.5 M ethanol, air, 2 M KOH Catalysts Table 5. Cont. Electrolyte/ T/°C OCV/V Imax/ mA cm−2 0.65 130 1.0 110 0.89 530 0.87 350 0.87 550 0.76 610 0.88 800 0.81 540 0.11 1 0.65 400 0.68 440 0.74 550 0.82 590 0.66 170 0.72 200 0.76 230 0.91 270 0.93 278 0.65 320 0.8 350 0.86 390 0.87 370 Pmax/ Ref. mW cm−2 18 [125] 30 [128] Pt/C 2 mg cm−2 PtRu/C 1.8mgcm membrane Pt/C ADP 2 mg cm−2 Pt/C Porous −2 2 mg cm separator Room T Room T 80 80 Room T 25 40 60 80 30 40 50 60 80 60 −2 DAAFC with non Pt catalyst, with alkaline 2 M KOH/ O2 10 wt% methanol 10 wt% ethanol 5 wt% glycerol 2 M KOH/O2 10 wt% methanol 10 wt% ethanol 5 wt% glycerol 2 M methanol, 0.05 M H2O2, 0.2M KOH 10 wt% ethanol, 2 M KOH / O2 1Methanol,1M KOH/O2 2Methanol,3M KOH/air 1 M EG, KOH /O2 1 M KOH 5 M KOH 7 M KOH 9 M KOH Pd/MWCN Fe-Co Tokuyama T HypermecTM A-210 1 mg cm−2 K-14 PdNiZn/C Fe-Co Tokuyama −2 TM 1mgcm Hypermec A-210 K-14 Ni(OH)2 Ag2O - PdNiZn/C Fe-Co Tokuyama −2 TM 1mgcm Hypermec A-210 K-14 TM TM Hypermec 2 Hypermec Tokuyama mgcm−2 1 mg cm−2 RuV/C TMPhP/C PBI/KOH −2 −2 4.5 mg cm 9mg cm TM PdNi Hypermec Tokuyama 2 mg cm−2 1 mg cm−2 95 74 79 [61] [61] 120 165 119 0.03 [127] 65 [61] 80 120 160 12 [98] 17 22 30 125 [118] [59] 35 53 67 60 6. Summary and Outlook Liquid alcohols have significantly higher energy densities than hydrogen, and they are easier to handle. These features make direct alcohol fuel cells a promising alternative low-cost power supply for portable electronics. Direct alkaline alcohol fuel cells can benefit from the more active reaction in alkaline media. Unlike conventional proton exchange membrane fuel cells, anion exchange membranes are used in present DAAFCs to transfer OH− within the membrane electrolyte. This will also reduce the carbonation process which shortens the fuel cell life time due to the reaction between CO2 and alkaline electrolyte, particularly with liquid electrolyte. Although the power output of DAAFCs is still lower than that of direct methanol fuel cells using proton exchange membranes, the performance of DAAFCs has improved significantly in the past decade. The developments on catalysts and anion exchange membranes provide a solid base for the further development of DAAFCs. Various alcohol fuels have been investigated for DAAFC applications. Alkaline media has particular advantages for poly carbon alcohols over acidic media because of higher reaction activity inPDF Image | Aspects of Direct Alkaline Alcohol Fuel Cells
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